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Question #44245
The Question
Consider the standard electrode potential for a 3d transition metal at . The thermodynamic parameters for the Born-Haber cycle of the half-reaction are given below:
Given the Faraday constant , calculate the standard reduction potential in Volts. (Assume standard state conditions and ideal behavior).
Options
- A.
- B.
- C.
- D.
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Mechanism_Trap
Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.
Concepts Behind This Question
Entropy of Phase Change|E° (M²⁺/M) Anomalies
Why This Question Is Tricky
Common Mistakes
This question targets the 'Enthalpy-Centric Bias' in evaluating standard electrode potentials.
Students frequently approximate for solid-state transitions, ignoring the significant entropy gain during the sublimation of complex metallic lattices (like Manganese) and the entropy loss during hydration due to solvent ordering.
Failing to account for the and terms leads to the incorrect 'enthalpy-only' value of .
Ignoring just the sublimation entropy yields .
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Thermodynamics - Class 11 Part 1 |
| Concept | Entropy of Phase Change |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |