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Question #45000
The Question
Compound is , a synthetic water-soluble conjugate of Vitamin C. A sample of is treated with excess Tollens' reagent (ammoniacal ) at , yielding of elemental silver precipitate. A separate sample of is subjected to complete acidic hydrolysis, carefully neutralized, and then treated with excess Tollens' reagent at , yielding of elemental silver precipitate. Assuming standard 2-electron oxidations for all reactive moieties, what are the values of and ?
Options
- A.
x = 0, y = 4
- B.
x = 2, y = 4
- C.
x = 0, y = 2
- D.
x = 2, y = 2
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Mechanism_Trap
Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.
Concepts Behind This Question
Vitamin Solubility Logic|Reducing Sugar Criteria|Glycosidic Linkage Geometry
Why This Question Is Tricky
Common Mistakes
The core trap is the assumption that any carbohydrate or Vitamin C derivative is inherently a reducing agent.
Students often memorize 'Vitamin C is a strong reducing agent' and 'Glucose is a reducing sugar' without analyzing the specific structural requirements (the free enediol for ascorbic acid and the free hemiacetal for glucose).
By linking them at their reactive centers (C-2 of ascorbic acid and C-1 of glucose), both moieties are locked.
Furthermore, the problem tests the stability of acetals in basic media (Tollens' reagent), preventing in situ hydrolysis, whereas deliberate acid hydrolysis restores the reducing power of both molecules, testing stoichiometric knowledge of the Tollens reaction.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Biomolecules - Class 12 |
| Concept | Vitamin Solubility Logic |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |