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Question #44897

Difficulty: 8/10 | 🟢 Free

The Question

Consider the following statements regarding the chemistry of f-block elements and their consequences:

I. Mischmetal is an alloy comprising ∼50%\sim 50\% \ceCe\ce{Ce}, ∼25%\sim 25\% \ceLa\ce{La}, along with \ceNd\ce{Nd}, \cePr\ce{Pr}, and ∼5%\sim 5\% \ceFe\ce{Fe}, widely used in \ceMg\ce{Mg}-based alloys for lighter flints. II. The post-lanthanoid transition metals \ceZr\ce{Zr} and \ceHf\ce{Hf} possess nearly identical atomic radii (160 pm160\text{ pm} and 159 pm159\text{ pm} respectively) primarily due to the poor shielding effect of 4f4f electrons. III. The basicity of lanthanoid hydroxides, \ceLn(OH)3\ce{Ln(OH)3}, increases from \ceLa(OH)3\ce{La(OH)3} to \ceLu(OH)3\ce{Lu(OH)3} due to the increase in covalent character of the \ceLn−OH\ce{Ln-OH} bond. IV. The separation of \ceZr(IV)\ce{Zr(IV)} and \ceHf(IV)\ce{Hf(IV)} is highly challenging because their identical principal quantum numbers for the valence d-orbitals lead to identical hydration enthalpies. V. The third ionization enthalpy (IE3IE_3) of \ceEu\ce{Eu} is anomalously high because the third electron must be removed from a highly stable, half-filled 4f74f^7 subshell.

Determine the total number of correct statements.

Options

  • A.

    2

  • B.

    3

  • C.

    4

  • D.

    5

Check Your Answer

Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Exception_Exposure

Learn to identify edge cases and boundary exceptions that JEE examiners hide in math problems.

Concepts Behind This Question

Mischmetal Composition|Post-Lanthanoid Radii Equality|D and F Block Elements

Why This Question Is Tricky

Common Mistakes

This question tests the student's ability to distinguish between the macroscopic consequences of the Lanthanoid Contraction (like the Zr/Hf radii equality and Mischmetal utility) and the underlying quantum mechanical reasons.

A common trap is assuming Zr and Hf have identical valence shell quantum numbers due to their identical chemical behavior, or misunderstanding the application of Fajan's rules to the basicity trend of lanthanoid hydroxides.

Quick Facts About This Question

Question Information

SubjectChemistry
ChapterD and F Block Elements - Class 12
ConceptMischmetal Composition
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree