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Question #44897
The Question
Consider the following statements regarding the chemistry of f-block elements and their consequences:
I. Mischmetal is an alloy comprising , , along with , , and , widely used in -based alloys for lighter flints. II. The post-lanthanoid transition metals and possess nearly identical atomic radii ( and respectively) primarily due to the poor shielding effect of electrons. III. The basicity of lanthanoid hydroxides, , increases from to due to the increase in covalent character of the bond. IV. The separation of and is highly challenging because their identical principal quantum numbers for the valence d-orbitals lead to identical hydration enthalpies. V. The third ionization enthalpy () of is anomalously high because the third electron must be removed from a highly stable, half-filled subshell.
Determine the total number of correct statements.
Options
- A.
2
- B.
3
- C.
4
- D.
5
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Exception_Exposure
Learn to identify edge cases and boundary exceptions that JEE examiners hide in math problems.
Concepts Behind This Question
Mischmetal Composition|Post-Lanthanoid Radii Equality|D and F Block Elements
Why This Question Is Tricky
Common Mistakes
This question tests the student's ability to distinguish between the macroscopic consequences of the Lanthanoid Contraction (like the Zr/Hf radii equality and Mischmetal utility) and the underlying quantum mechanical reasons.
A common trap is assuming Zr and Hf have identical valence shell quantum numbers due to their identical chemical behavior, or misunderstanding the application of Fajan's rules to the basicity trend of lanthanoid hydroxides.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | D and F Block Elements - Class 12 |
| Concept | Mischmetal Composition |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |