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Question #44698

Difficulty: 8/10 | 🟢 Free

The Question

In a high-energy spectroscopic experiment, a hydrogen-like ion XZ+X^{Z+} undergoes an electronic transition from n=n2n=n_2 to n=n1n=n_1, emitting a photon of energy Eγ=hcRHZ2(1n12−1n22)E_\gamma = h c R_H Z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right). This photon is incident on a metallic target with a work function Φ\Phi, ejecting a photoelectron. If the atomic number ZZ is sufficiently large such that the maximum kinetic energy of the ejected photoelectron is a significant fraction of its rest mass energy (m0c2m_0 c^2), which of the following expressions accurately represents the exact de Broglie wavelength (λe\lambda_e) of the fastest ejected photoelectron?

Options

  • A.

    hc(Eγ−Φ)2+2m0c2(Eγ−Φ)\frac{hc}{\sqrt{(E_\gamma - \Phi)^2 + 2m_0 c^2 (E_\gamma - \Phi)}}

  • B.

    h2m0(Eγ−Φ)\frac{h}{\sqrt{2m_0 (E_\gamma - \Phi)}}

  • C.

    hcEγ2+2m0c2Eγ\frac{hc}{\sqrt{E_\gamma^2 + 2m_0 c^2 E_\gamma}}

  • D.

    hcEγ−Φ\frac{hc}{E_\gamma - \Phi}

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Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Mechanism_Trap

Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.

Concepts Behind This Question

Rydberg Equation Constants|De Broglie Wavelength Logic

Why This Question Is Tricky

Common Mistakes

This problem tests the intersection of Quantum Transitions, the Photoelectric Effect, and Relativistic Mechanics.

The 'Hidden Variable' is the breakdown of the classical momentum approximation (p=2mKp = \sqrt{2mK}) at high energies.

Students fall into three traps: 1) Using the non-relativistic de Broglie formula (Option B), ignoring the relativistic mass increase. 2) Forgetting the work function Φ\Phi and assuming all photon energy converts to kinetic energy (Option C). 3) Conflating the wave-particle duality of massless photons (E=pcE=pc) with massive electrons, leading to λ=hc/K\lambda = hc/K (Option D).

Quick Facts About This Question

Question Information

SubjectChemistry
ChapterStructure of Atom - Class 11 Part 1
ConceptRydberg Equation Constants
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree