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Question #44698
The Question
In a high-energy spectroscopic experiment, a hydrogen-like ion undergoes an electronic transition from to , emitting a photon of energy . This photon is incident on a metallic target with a work function , ejecting a photoelectron. If the atomic number is sufficiently large such that the maximum kinetic energy of the ejected photoelectron is a significant fraction of its rest mass energy (), which of the following expressions accurately represents the exact de Broglie wavelength () of the fastest ejected photoelectron?
Options
- A.
- B.
- C.
- D.
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Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Mechanism_Trap
Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.
Concepts Behind This Question
Rydberg Equation Constants|De Broglie Wavelength Logic
Why This Question Is Tricky
Common Mistakes
This problem tests the intersection of Quantum Transitions, the Photoelectric Effect, and Relativistic Mechanics.
The 'Hidden Variable' is the breakdown of the classical momentum approximation () at high energies.
Students fall into three traps: 1) Using the non-relativistic de Broglie formula (Option B), ignoring the relativistic mass increase. 2) Forgetting the work function and assuming all photon energy converts to kinetic energy (Option C). 3) Conflating the wave-particle duality of massless photons () with massive electrons, leading to (Option D).
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Structure of Atom - Class 11 Part 1 |
| Concept | Rydberg Equation Constants |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |