Before You Begin
Question #44328
The Question
Cobalt(II,III) oxide (\ce{Co3O4}) is a mixed-valence compound that crystallizes in a normal spinel structure. The successive ionization energies for gaseous cobalt atoms are given as: , , . Calculate the total ionization energy required to form the constituent cobalt cations present in one mole of \ce{Co3O4} from gaseous cobalt atoms. Additionally, determine the total Crystal Field Stabilization Energy (CFSE) of these cations in their respective lattice sites. (Assume oxide acts as a strong field ligand for \ce{Co^{3+}} and a weak field ligand for \ce{Co^{2+}}. Ignore pairing energy in the final expression, and use ).
Options
- A.
- B.
- C.
- D.
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Numerical_Precision
Improve calculation stamina and avoid rounding errors in high-stakes competitive examinations.
Concepts Behind This Question
d-block Variable Oxidation States|Fractional Oxidation State Misconception|Successive Ionization Energies
Why This Question Is Tricky
Common Mistakes
This problem tests the 'Fractional Oxidation State Misconception' by requiring students to deconstruct a mixed-valence oxide into its exact crystallographic oxidation states (+2 and +3 in a 1:2 ratio) rather than using an average +8/3 state.
It forces a synthesis of atomic energetics (successive ionization energies) and coordination chemistry.
The trap lies in assuming an inverse spinel structure (common for Fe3O4) or failing to recognize that the higher oxidation state of Co(III) induces a low-spin complex even with a weak-field ligand like oxide, which dictates the normal spinel preference and drastically alters the CFSE calculation.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Classification of Elements and Periodicity in Properties - Class 11 Part 1 |
| Concept | d-block Variable Oxidation States |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |