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Question #44188

Difficulty: 8/10 | 🟢 Free

The Question

A sample of a radioactive metal M(s)M_{(s)} (Work function Φ=4.2\Phi = 4.2 eV) undergoes α\alpha-decay with a half-life of 120120 days. The sample is placed in a vacuum chamber at 298298 K and continuously irradiated with monochromatic light of wavelength λ=248.4\lambda = 248.4 nm and power P=2.56×10−3P = 2.56 \times 10^{-3} W. The photoelectric quantum efficiency (ratio of emitted photoelectrons to incident photons) is 2.5×10−52.5 \times 10^{-5}.

The emitted α\alpha-particles completely strike a \ce9Be(s)\ce{^9Be_{(s)}} target, triggering the nuclear reaction: \ce9Be+4He−>12C+1n\ce{^9Be + ^4He -> ^{12}C + ^1n} (100%100\% yield).

Given the initial α\alpha-activity of the sample is 1.28×10121.28 \times 10^{12} Bq, and assuming the nuclei are stable against photon-induced transmutation (i.e., the nuclear decay constant is independent of the electronic ionization state), after how many days will the rate of neutron production exactly equal the rate of photoelectron emission?

(Given: hc=1242hc = 1242 eV nm, 11 eV =1.6×10−19= 1.6 \times 10^{-19} J)

Options

  • A.

    480480 days

  • B.

    692692 days

  • C.

    240240 days

  • D.

    ∞\infty days

Check Your Answer

Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Numerical_Precision

Improve calculation stamina and avoid rounding errors in high-stakes competitive examinations.

Concepts Behind This Question

Photoelectric Effect Threshold|Radioactive Decay as Kinetics|First Order Half-Life Independence

Why This Question Is Tricky

Common Mistakes

This problem tests the intersection of the Photoelectric Effect and First-Order Nuclear Kinetics.

The core 'Chemical Exception' or 'Hidden Variable' being tested is 'First Order Half-Life Independence'.

Students often fall into the trap of assuming that continuous photon irradiation and subsequent electron loss (ionization) will alter the nuclear decay constant, or they mistakenly subtract the photoelectron emission rate from the nuclear activity, treating them as parallel kinetic pathways.

The problem forces the realization that nuclear decay is an intrinsic property, completely independent of the atom's extrinsic electronic state.

Additionally, it tests the threshold energy condition; failing to convert units properly leads to the erroneous conclusion that no emission occurs, pointing to the distractor of infinite days.

Quick Facts About This Question

Question Information

SubjectChemistry
ChapterStructure of Atom - Class 11 Part 1
ConceptPhotoelectric Effect Threshold
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree