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Question #43618

Difficulty: 8/10 | 🟢 Free

The Question

A non-linear polyatomic ideal gas, consisting of molecules of mass mm, is in thermal equilibrium at absolute temperature TT. Each molecule has exactly 66 active degrees of freedom (33 translational and 33 rotational, with all vibrational modes frozen). If EE represents the average total energy per molecule, which of the following expressions gives the effective thermal de Broglie wavelength (λ\lambda) of the gas molecules based on their root-mean-square momentum? (Here hh is Planck's constant)

Options

  • A.

    hmE\frac{h}{\sqrt{mE}}

  • B.

    h2mE\frac{h}{\sqrt{2mE}}

  • C.

    h3mE\frac{h}{\sqrt{3mE}}

  • D.

    h6mE\frac{h}{\sqrt{6mE}}

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Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Multi-Concept_Bridge

Master problems that require linking physics and math concepts to solve complex competitive questions.

Concepts Behind This Question

De Broglie Wavelength Scaling|Molecular Degrees of Freedom|Kinetic Theory

Why This Question Is Tricky

Common Mistakes

This question tests the student's understanding of the Equipartition Theorem and its application to the de Broglie wavelength.

A common trap is assuming that the total internal energy of a polyatomic molecule contributes to its translational momentum, leading to the incorrect use of p=2mEp = \sqrt{2mE} (Option B).

Students must recognize that the de Broglie wavelength is determined strictly by the translational degrees of freedom (f=3f=3), which partition only a fraction of the total energy (Ktrans=E/2K_{\text{trans}} = E/2 for f=6f=6).

By expressing the wavelength in terms of total energy EE, the problem forces students to explicitly decouple translational kinetic energy from rotational kinetic energy.

Quick Facts About This Question

Question Information

SubjectPhysics
ChapterDual Nature of Radiation and Matter - Class 12
ConceptDe Broglie Wavelength Scaling
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree