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Question #42592

Difficulty: 8/10 | 🟢 Free

The Question

A rigid, adiabatic container of total volume VV is divided by a thin, insulating partition. One side contains 44 moles of a monatomic ideal gas at 240 K240\text{ K}, and the inner walls in contact with this gas have a heat capacity of Ccal=4RC_{cal} = 4R. The other side contains 22 moles of a diatomic ideal gas at 900 K900\text{ K} (the walls on this side have negligible heat capacity). The partition is removed, allowing the gases to mix and reach thermal equilibrium. For the diatomic gas, vibrational degrees of freedom are completely frozen below 600 K600\text{ K} and fully active at or above 600 K600\text{ K} (assume a sharp transition). What is the final partial pressure of the diatomic gas? (RR is the universal gas constant).

Options

  • A.

    1000RV\frac{1000 R}{V}

  • B.

    920RV\frac{920 R}{V}

  • C.

    3000RV\frac{3000 R}{V}

  • D.

    1189RV\frac{1189 R}{V}

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Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Multi-Concept_Bridge

Master problems that require linking physics and math concepts to solve complex competitive questions.

Concepts Behind This Question

Dalton's Law of Partial Pressures|Temperature and Kinetic Energy|Calorimetry with Heat Loss|Energy of Vibrational Modes

Why This Question Is Tricky

Common Mistakes

This question tests the application of the Equipartition Theorem across temperature thresholds and Dalton's Law of partial pressures.

The primary trap is assuming a constant degree of freedom (f=5f=5) for the diatomic gas, ignoring the activation of vibrational modes at higher temperatures, which leads to an incorrect equilibrium temperature of 460 K.

Secondary traps include neglecting the calorimeter's heat capacity (a common oversight in adiabatic container problems, leading to 594.5 K) and calculating the total pressure of the mixture instead of the requested partial pressure of the diatomic gas.

Quick Facts About This Question

Question Information

SubjectPhysics
ChapterKinetic Theory - Class 11 Part 2
ConceptDalton's Law of Partial Pressures
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree