Before You Begin
Question #42592
The Question
A rigid, adiabatic container of total volume is divided by a thin, insulating partition. One side contains moles of a monatomic ideal gas at , and the inner walls in contact with this gas have a heat capacity of . The other side contains moles of a diatomic ideal gas at (the walls on this side have negligible heat capacity). The partition is removed, allowing the gases to mix and reach thermal equilibrium. For the diatomic gas, vibrational degrees of freedom are completely frozen below and fully active at or above (assume a sharp transition). What is the final partial pressure of the diatomic gas? ( is the universal gas constant).
Options
- A.
- B.
- C.
- D.
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Multi-Concept_Bridge
Master problems that require linking physics and math concepts to solve complex competitive questions.
Concepts Behind This Question
Dalton's Law of Partial Pressures|Temperature and Kinetic Energy|Calorimetry with Heat Loss|Energy of Vibrational Modes
Why This Question Is Tricky
Common Mistakes
This question tests the application of the Equipartition Theorem across temperature thresholds and Dalton's Law of partial pressures.
The primary trap is assuming a constant degree of freedom () for the diatomic gas, ignoring the activation of vibrational modes at higher temperatures, which leads to an incorrect equilibrium temperature of 460 K.
Secondary traps include neglecting the calorimeter's heat capacity (a common oversight in adiabatic container problems, leading to 594.5 K) and calculating the total pressure of the mixture instead of the requested partial pressure of the diatomic gas.
Quick Facts About This Question
Question Information
| Subject | Physics |
| Chapter | Kinetic Theory - Class 11 Part 2 |
| Concept | Dalton's Law of Partial Pressures |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |