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Question #42174

Difficulty: 8/10 | 🟢 Free

The Question

A cylinder contains one mole of a rigid diatomic ideal gas at equilibrium pressure P0P_0 and volume V0V_0. A piston drives the volume to oscillate as V(t)=V0−ΔVcos⁡(ωt)V(t) = V_0 - \Delta V \cos(\omega t), where ΔV≪V0\Delta V \ll V_0. The translational degrees of freedom equilibrate instantaneously, but the rotational degrees of freedom have a relaxation time τ\tau. The effective molar heat capacity at constant volume is given by CV(ω)=CV,trans+CV,rot1+ω2τ2C_V(\omega) = C_{V,trans} + \frac{C_{V,rot}}{1 + \omega^2 \tau^2}. Assuming the process follows an effective adiabatic relation PVγeff=constantP V^{\gamma_{eff}} = \text{constant} with γeff=1+RCV(ω)\gamma_{eff} = 1 + \frac{R}{C_V(\omega)}, what is the amplitude of the pressure oscillations ΔP0\Delta P_0 when the piston is driven at a frequency ω=1τ\omega = \frac{1}{\tau}?

Options

  • A.

    32P0V0ΔV\frac{3}{2} \frac{P_0}{V_0} \Delta V

  • B.

    75P0V0ΔV\frac{7}{5} \frac{P_0}{V_0} \Delta V

  • C.

    53P0V0ΔV\frac{5}{3} \frac{P_0}{V_0} \Delta V

  • D.

    43P0V0ΔV\frac{4}{3} \frac{P_0}{V_0} \Delta V

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Correct Answer

Step-by-Step Solution

Explanation

How the Examiner Thinks

Intuition_Breaker

Train your brain to resist "obvious" answers that are designed to deceive your intuition.

Concepts Behind This Question

Internal Energy Dependency|Driven Oscillations and Resonance|Differential Equations

Why This Question Is Tricky

Common Mistakes

This question tests the application of the Equipartition Theorem in non-equilibrium thermodynamics during driven oscillations.

The 'Lethal Collision' occurs when students assume internal energy and heat capacity are strictly state functions independent of the process rate, defaulting to the static diatomic adiabatic exponent γ=7/5\gamma = 7/5.

By driving the piston at a frequency comparable to the rotational relaxation time (ω≈1/τ\omega \approx 1/\tau), the rotational degrees of freedom partially 'freeze out', leading to a frequency-dependent effective heat capacity and a modified adiabatic bulk modulus.

Quick Facts About This Question

Question Information

SubjectPhysics
ChapterThermodynamics - Class 11 Part 2
ConceptInternal Energy Dependency
Difficulty8
Cognitive Load7
Target Solve Time160 sec
AccessFree